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How can we export Alfresco site users and their corresponding access privileges as CSV files?
Out of the box you cannot - you would have to write some custom script / code for that (a customer of mine did that a few years ago, though it was a suboptimal script that does not scale well with large data structures). There is an older addon that was commercially available via the German ecm4u Alfresco implementer (https://hub.alfresco.com/t5/alfresco-content-services-add/ecm4u-permissions/td-p/291550) - not sure if that was updated to a newer Alfresco version and remains available.