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Yes definitely. Alfresco supports INBOUND, UPDATE and OUTBOUND rule triggers, which means that you can execute actions when those triggers occur on a document/folder. The actions can do all sorts of things such as move/copy items to a another folder (which could be shared on a webserver using the CIFS interface) or execute a script. Alfresco has FTP support also, so you could use rules to copy/move items to a folder that you have set a cron job or similar to FTP files out of a specific folder and so on.
